This PR was fixed by r12-221-ge1543e694dadf1ea70eb72325219bc0cdc914a35
(for compilers that support C++20 Concepts) so this adds the testcase.
libstdc++-v3/ChangeLog:
PR libstdc++/97930
* testsuite/20_util/pair/requirements/structural.cc: New test.
--- /dev/null
+// { dg-options "-std=gnu++20" }
+// { dg-do compile { target c++20 } }
+
+#include <utility>
+
+// C++20 20.4.2 [pairs.pair]
+// pair<T, U> is a structural type (13.2) if T and U are both structural types.
+
+template<std::pair<int, int>> struct S; // PR libstdc++/97930