pp_subst: cosmetic re-arrangement of vars

pp_subst: cosmetic re-arrangement of vars

since 'orig' always points to the start of the string, while 's' varies,
change

    s = SvPV_nomg(...);
    ...other stuff using value of s ...
    orig = s
    ...

to

    orig = SvPV_nomg(...);
    ...other stuff using value of orig ...
    s = orig
    ...

No functional change, just reduces the cognitive load slightly

also adds some comments as to what force_on_match is about.